[mssa] Fix case when there is no definition in a block prior to an inserted use.

Summary:
Check that the first access before one being tested is valid.
Before this patch, if there was no definition prior to the Use being tested,
the first time Iter was deferenced, it hit the sentinel.

Reviewers: dberlin, gbiv

Subscribers: sanjoy, Prazek, llvm-commits

Differential Revision: https://reviews.llvm.org/D33950

llvm-svn: 304926