[PGO] Avoid instrumenting direct callee's at value sites.

Direct callees' that are cast to other function prototypes,
show up in the Call/Invoke instructions as ConstantExpr's.
Currently llvm::CallSite's getCalledFunction() fails
to return the callees in such expressions as direct calls.
Value profiling should avoid instrumenting such cases. Mostly NFC.

llvm-svn: 265330