Part of PR39508: Emit an @llvm.invariant.start after storing to

__tls_guard.

__tls_guard can only ever transition from 0 to 1, and only once. This
permits LLVM to remove repeated checks for TLS initialization and
repeated initialization code in cases like:

  int g();
  thread_local int n = g();
  int a = n + n;

where we could not prove that __tls_guard was still 'true' when checking
it for the second reference to 'n' in the initializer of 'a'.

llvm-svn: 345774